内容简介
本书是唯一一本介绍固体无机化合物尤其是金属氧化物化学平衡的著作。对没有多少缺陷化学背景的学生而言，本书解释了如何应用基本原理以及如何解释材料的相关行为。本书讨论的主题包括晶格和电子缺陷、掺杂效应、非化学计量性以及质量与电荷的输运，特别强调了成分元素的一般化学性能与它们的化合物的缺陷化学和输运性能之间的关系。本书覆盖了缺陷形成种类、掺杂效应、化学计量的偏离程度和方向、受主和施主浓度以及其他主题。最后一章对二氧化钛、氧化钴和氧化镍以及钛酸钡这三个体系做了最新的介绍和详细的分析。本书是同类出版物中唯一一本为学生设计了习题的教材。它可满足材料科学与工程、化学和地球化学等学科中不同课程的需要，同时也可以作为研究人员和教师的有益的参考书。
本书作者
D．M．Smyth，生于1930年，现为美国里海大学(Lehigh University)保罗·B·莱因霍尔德(Paul B．Reinhold)材料科学与工程和化学荣誉退休教授。研究方向为电子陶瓷中的固态化学和缺陷化学。1990年当选美国陶瓷学会会士。1996年因其在电子陶瓷元件中的固态化学方面所做出的杰出贡献当选美国国家工程院院士。
目录
Preface
1.Introduction
Reference
2.A Few Useful Cryst0al Structures
Introduction
Close-Packed Structures
Structures for Einght-Coordinate Cations
Structures for Ternary Compounds
Conclusion
References
Pnoblems
3.Lattice Defects and the Law of Mass Action
Introduction
Lattice Defects as Part of the Equilibrium State
The Law of Mass Action
Anoter View of Mass Actiom
Lattice Disorder in Elemental Solids
Summary
References
4.Intrinsic Ionic Disorder
Lattice Defects and Reference States
onservation Rules
Defect Notation
Major Types of Intrinsic Ionic Disorder
General Comments on Intrinsic Ionic Disorder
References
Problems
5.Extrinsic Ionic Disorder
Introduction
The AgCl-CdCls System
The CaF2CaO System
The TiO2-Nb2O5System
Summary of Important Points
Schematic Representation of Defect Concentrations
Sunmmary of Extrinsic Ionic Disorder
References
Problems
6.Defect Complexes and Associates
Introducation
Complexes Containing an Impurity Center and an Ionic Defect
Intrinsic Ionic Defect Associates
The Effect of Impurities on the COncentrations of Defect COmplexes and Associates
REferences
7.Ionic Transport
Introduction
Basic Concepts of Diffusion
Ionic Conducation in Crystalline Solids
Intrinsic and Extrinsic Ionic Conduction
Fast Ion Conductors
Referencess
8.Intrinsic Electronic Disorder
Introduction
The Development of Energy Bands
The Mass-Action Approach
The Fermi Function
Holes Waves and Effective Masses
Electronic Conductivity
Hopping Mechanisms
The Band Structure of Compounds
Chemistry and the Band Gap
Summary
References
9.Extrinsic Electronic Disorder
10.Intrnsic Nonstoichiometry
11.Extrinsic Nonstoichiometry
12.Titanium Dioxide
13.Cobalt Oxide and Nickel Oxide
14.Barium Titanate
15.Order versus Disorder
Index
